Using a photocatalyst to move ortho- and para-substituents one atom along a pyridine ring could simplify how chemists make meta-substituted aromatic molecules, a key scaffold for several drug ...
Organometallic compounds tend to marry metals with aromatic hydrocarbons so that the metal sits above or below the carbon-based group’s flat plane and interacts with the hydrocarbon’s p orbitals. The ...
Team discovers electrochemical method for highly selective single-carbon insertion in aromatic rings
This illustration visualizes a novel electrochemical transformation in which a single carbon atom—derived from a diazo compound—is selectively inserted into the pyrrole ring via a distonic radical ...
Nuclear magnetic resonance (NMR) spectroscopy has emerged as an indispensable tool in elucidating protein dynamics at atomic resolution. In particular, studies on aromatic side chains have revealed ...
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